O Levels Combined Chemistry G3 O Levels G3 Combined Chemistry Paper 1 mock Name 1 / 20 Which statement does not explain why the speed of the reaction between zinc and dilute sulfuric acid increases when the acid is warmed? The particles are moving faster as they gain more energy. The activation energy of the reaction decreases. The particles are colliding more frequently. More particles have sufficient energy required for the reaction. An alternative pathway with lower activation energy is only provided by a catalyst, not a higher temperature 2 / 20 Which of the following statements about a homologous series is correct? The melting and boiling point increases with increasing relative molecular mass. The members have similar physical properties. The members have the same molecular formula. The relative molecular masses of consecutive members differ by 12. The physical properties of members show a trend 3 / 20 The following chemicals are available in the laboratory. aqueous bromine Universal Indicator solution magnesium powder sodium carbonate Which of these chemicals can be used to distinguish between propene and propanoic acid? All of them 1 only 1 and 4 only 1, 2 and 3 only aqueous bromine --> change colourless/no change Universal Indicator solution --> turns orange/ green magnesium powder --> no change/effervescence sodium carbonate --> no change/effervescence 4 / 20 On adding 50 g of impure limestone, CaCO3 (Mr = 100), to excess hydrochloric acid, 6.0 dm3 of CO2 was evolved at room temperature and pressure. What is the percentage purity of the limestone? 25% 50% 75% 100% CaCO3 + 2HCl --> CaCl2 + CO2 + H2O for CO2: 24dm3 --> 1 mole 6 dm3 --> 0.25 mole mole ratio of CO2 : CaCO3 1 : 1 0.25 : 0.25 Molar Mass of CaCO3 = 100g 0.25 mole --> 25g Therefore, % purity = (25/50) x 100% = 50 % 5 / 20 Which statement is correct? 1.00 mol of zinc chloride contains 1.20 × 10^24 ions. 2.00 mol of sodium nitrate contains 1.20 × 10^24 ions. 24.0 dm3 of chlorine gas, measured at room temperature and pressure, contains 1.20 × 10^24 atoms. 48.0 dm3 of hydrogen gas, measured at room temperature and pressure, contains 1.20 × 10^24 atoms. 1 mole of any gas at rtp is 24 dm^3. therefore 24 dm^3 of chlorine gas has 1 mole of cl2 molecules which is 2 mole of atoms = 2 x 6 x10^23 = 1.2 x 10 ^24 6 / 20 Three elements W, X, Y, and Z have consecutive, increasing proton (atomic) numbers. Element Y exists as a colourless, monatomic gas at room temperature. Which will be the chemical formula of a compound formed between W and chlorine? WCl W2Cl WCl2 W2Cl3 Y would be noble gas and thus W is in group 16 with 6 valence electrons and need 2 more Cl has 7 valence and need 1 more so the formula will be WCl2 7 / 20 Hydrogen gas reacts with chlorine gas to form hydrogen chloride gas. H2(g) + Cl2(g) → 2HCl(g) What is the final volume of the gas mixture when 20 dm3 of hydrogen is reacted with 30 dm3 of chlorine gas at 100 C? 40 dm3 50 dm3 60 dm3 70 dm3 H2(g) + Cl2(g) → 2HCl(g) hydrogen gas is limiting reagent. Cl2 gas is excess by 10 dm3 Vol of HCl produced = 2 x 20 dm3 = 40 dm3 Final volume = 40 + 10 = 50 dm3 8 / 20 The diagram shows the apparatus used to separate hexane (boiling point, 70 oC) and heptane (boiling point, 98 oC). A B C D Heptane vapour will condense as it reaches the fractionating column; only hexane vapour will reach the condenser. As the thermometer will only measure the inlet of the condenser, the measured temperature will be constant at the boiling point of hexane until all the hexane has vaporized. 9 / 20 When a 10 cm3 sample of a gaseous hydrocarbon was completely burnt in 35 cm3 of oxygen, the total volume of the products formed was 50 cm3. Which equation represents the combustion of the hydrocarbon? CH4(g) + 2O2(g) → CO2(g) + 2H2O(g) C2H4(g) + 3O2(g) → 2CO2(g) + 2H2O(g) C3H8(g) + 5O2(g) → 3CO2(g) + 4H2O(g) 2C2H6(g) + 7O2(g) → 4CO2(g) + 6H2O(g) Since all the reactants and products are gases, we can use the ratio of volume directly without converting to moles. 10: 35 : 50 2 : 7 : 10 ratio of hydrocarbon is 2, ratio of oxygen is 7 and ratio of the sum of products is 10. Only D satisfy this ratio 10 / 20 The structure of brass is shown below. What is the purpose of adding zinc to copper? to make the packing of atoms more compact to strengthen the metallic bonds between copper atoms to prevent layers of copper atoms from sliding over each other easily to prevent the ‘sea of electrons’ from moving freely in the metal lattice Adding zinc atoms to copper disrupts the orderly arrangement, which prevents layers of copper atoms from sliding over each other easily. The effect is that the alloy is now harder and stronger than pure copper. 11 / 20 Elements X and Y combine to form an ionic compound. Atoms of X have more protons than atoms of Y. Atoms of Y have more valence electrons than atoms of X. Which statement is correct? Ions of X are negatively charged. Atoms of X have more electron shells than atoms of Y. X and Y are in the same period of the Periodic Table. X and Y are in the same group of the Periodic Table. X and Y, one is metal, one is non-metal. since Y has more valence then X is metal and Y is non-metal and X has more electron shell since it has protons. 12 / 20 An impure sample of calcium carbonate with a mass of 1.70 g was reacted with excess hydrochloric acid and 360 cm3 of carbon dioxide was collected at room temperature and pressure. What is the percentage purity of the calcium carbonate? 75% 88% 90% 98% CaCO3 + 2HCl --> CaCl2 + CO2 + H2O 1 mole --> 24000 cm3 360 cm3 --> 0.015 mole Ratio of CaCO3 : CO2 1:1 mole of CaCO3 = 0.015 mole molar mass of CaCO3 = 100g mass = 0.015 x 100 = 1.5g % purity = 1.5/1.7 x 100% = 88.2% 13 / 20 Which property of elements increases from left to right of Period 3 of the Periodic Table? number of outer shells metallic character tendency to get reduced melting points As you move from left to right across a period, the number of protons in the nucleus increases, which leads to a stronger attraction for electrons. This increased attraction makes it more difficult for an atom to lose electrons, 14 / 20 Oxygen was prepared and collected using the apparatus as shown in the diagram below. The first tube of gas collected was discarded as it was contaminated. Which contaminant was in the gas? hydrogen hydrogen peroxide manganese(IV) oxide nitrogen There would be air in the test tube and tubing. Thus the main contaminant would be nitrogen gas. 15 / 20 In which chemical reaction does the named product have a higher relative molecular mass than the reactant? the formation of ethanol from glucose the formation of propene from octane the formation of carbon dioxide from butane the formation of dichloromethane from methane methane CH4 molar mass = 12 +4 = 16g dichloromethan CH2Cl2 molar mass = 12 +2 + 71 = 85g 16 / 20 Which of the following hydrocarbons would produce the sootiest flame when burnt in air? CH4 C4H10 C8H18 C12H26 The more C atoms in the molecule, the more soot (unburnt hydrocarbon) will be produced 17 / 20 An element T forms an ion, T2+, which has an electronic arrangement 2.8.8. Which statement(s) concerning T is/are correct? I T is an alkali metal. II T forms a basic oxide with oxygen. III T is in Period 4 of the Periodic Table. I and II only I and III only II and III only I , II and III Since its ion's charge is 2+, it is in group 2 and called Alkali Earth metal not alkali metal. 2,8,8,2 is calcium which is in period 4 as its atom have 4 electron shells. Its oxide is basic. 18 / 20 A reaction takes place in two stages in the presence of a catalyst: Which ion is the catalyst in the reaction? Fe^2+ (aq) I^– (aq) SO4^2– (aq) S2O8^2– (aq) The catalyst must remain unchanged at the end of the reaction. 19 / 20 Which of these Group 1 elements reacts most violently with water? caesium lithium potassium rubidium reactivity increases as it goes down the group. 20 / 20 Which substances contain the same number of atoms? A B C D Your score isThe average score is 85% 0% Restart quiz
